We study the spectrum of the Dirac Hamiltonian in one space dimension for a single
electron in the electrostatic potential of a point nucleus, in the Born–Oppenheimer
approximation where the nucleus is assumed fixed at the origin. The potential is screened
at large distances so that it goes to zero exponentially at spatial infinity. We show
that the Hamiltonian is essentially self-adjoint, the essential spectrum has the usual
gap
in it, and that there are only finitely many eigenvalues in that gap, corresponding to
ground and excited states for the system. We find a one-to-one correspondence
between the eigenfunctions of this Hamiltonian and the heteroclinic saddle-saddle
connectors of a certain dynamical system on a finite cylinder. We use this
correspondence to study how the number of bound states changes with the nuclear
charge.
Keywords
Dirac's equation, relativistic Hamiltonian, hydrogen
spectrum, one-dimensional quantum system