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One-dimensional hydrogenic ions with screened nuclear Coulomb field

Suchindram Dasgupta, Chirag Khurana and A. Shadi Tahvildar-Zadeh

Vol. 19 (2026), No. 4, 593–632
Abstract

We study the spectrum of the Dirac Hamiltonian in one space dimension for a single electron in the electrostatic potential of a point nucleus, in the Born–Oppenheimer approximation where the nucleus is assumed fixed at the origin. The potential is screened at large distances so that it goes to zero exponentially at spatial infinity. We show that the Hamiltonian is essentially self-adjoint, the essential spectrum has the usual gap (−mc2,mc2) in it, and that there are only finitely many eigenvalues in that gap, corresponding to ground and excited states for the system. We find a one-to-one correspondence between the eigenfunctions of this Hamiltonian and the heteroclinic saddle-saddle connectors of a certain dynamical system on a finite cylinder. We use this correspondence to study how the number of bound states changes with the nuclear charge.

Keywords
Dirac's equation, relativistic Hamiltonian, hydrogen spectrum, one-dimensional quantum system
Mathematical Subject Classification
Primary: 34B24, 35Q40, 37J46, 47A75, 81Q10
Secondary: 37L10
Milestones
Received: 30 July 2024
Revised: 2 March 2025
Accepted: 10 March 2025
Published: 13 October 2026

Communicated by Martin Bohner
Authors
Suchindram Dasgupta
Department of Physics and Astronomy
West Virginia University
Morgantown, WV
United States
Chirag Khurana
Applied Physics & Applied Mathematics Department
Columbia University
New York, NY
United States
A. Shadi Tahvildar-Zadeh
Department of Mathematics
Rutgers University (New Brunswick)
Piscataway, NJ
United States