In this article we shall
prove that the enveloping algebra of the Lie algebra of a class of unimodular
Lie groups having discrete series, when localized at some element of the
center, is isomorphic to the tensor product of a Weyl algebra over the ring of
Laurent polynomials of one variable and the enveloping algebra of some
reductive algebra. In particular, it will be proved that the Lie algebra of a
unimodular solvable Lie group having discrete series satisfies the Gelfand-Kirillov
conjecture.