Let Γ be a free group on
infinitely many generators. Fix a basis for Γ and for any group element x, denote by
|x| its length with respect to this basis. Let e denote the group identity. A
multiplicative function ϕ on Γ is a function satisfying the conditions ϕ(e) = 1 and
ϕ(xy) = ϕ(x)ϕ(y) whenever |xy| = |x| + |y|. We characterize those positive
definite multiplicative functions for which the associated representation of Γ is
irreducible.