We study the transverse
Poisson structure to adjoint orbits in a complex semisimple Lie algebra. The problem
is first reduced to the case of nilpotent orbits. We prove then that in suitably chosen
quasihomogeneous coordinates, the quasidegree of the transverse Poisson structure is
−2. For subregular nilpotent orbits, we show that the structure may be computed
using a simple determinantal formula that involves the restriction of the Chevalley
invariants on the slice. In addition, using results of Brieskorn and Slodowy, the
Poisson structure is reduced to a three dimensional Poisson bracket, which is
intimately related to the simple rational singularity that corresponds to the
subregular orbit.