Using basic homotopy
constructions, we show that isomorphism classes of string structures on spin bundles
are naturally given by certain degree 3 cohomology classes, which we call string
classes, on the total space of the bundle. Using a Hodge isomorphism, we then show
that the harmonic representative of a string class gives rise to a canonical 3-form on
the base space, refining the associated differential character. We explicitly calculate
this 3-form for homogeneous metrics on 3-spheres, and we discuss how the
cohomology theory tmf could potentially encode obstructions to positive Ricci
curvature metrics.