Vol. 1, No. 1, 2020

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Mean-field tricritical polymers

Roland Bauerschmidt and Gordon Slade

Vol. 1 (2020), No. 1, 167–204
Abstract

We provide an introductory account of a tricritical phase diagram, in the setting of a mean-field random walk model of a polymer density transition, and clarify the nature of the density transition in this context. We consider a continuous-time random walk model on the complete graph, in the limit as the number of vertices N in the graph grows to infinity. The walk has a repulsive self-interaction, as well as a competing attractive self-interaction whose strength is controlled by a parameter g. A chemical potential ν controls the walk length. We determine the phase diagram in the (g,ν) plane, as a model of a density transition for a single linear polymer chain. A dilute phase (walk of bounded length) is separated from a dense phase (walk of length of order N) by a phase boundary curve. The phase boundary is divided into two parts, corresponding to first-order and second-order phase transitions, with the division occurring at a tricritical point. The proof uses a supersymmetric representation for the random walk model, followed by a single block-spin renormalisation group step to reduce the problem to a 1-dimensional integral, followed by application of the Laplace method for an integral with a large parameter.

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Keywords
polymer model, complete graph, mean field, phase transition, tricritical point, theta point
Mathematical Subject Classification 2010
Primary: 82B27, 82B41
Secondary: 60K35
Milestones
Received: 1 November 2019
Accepted: 24 April 2020
Published: 16 November 2020
Authors
Roland Bauerschmidt
Department of Pure Mathematics and Mathematical Statistics
University of Cambridge
Wilberforce Road
Cambridge
United Kingdom
Gordon Slade
Department of Mathematics
University of British Columbia
Vancouver BC
Canada