We investigate the rheological behavior of nanosilica/PEG200-based shear thickening
fluids (STFs), focusing on their temperature-dependent characteristics over the range of
–C.
Results show that increasing temperature significantly reduces both the
peak viscosity and shear stress while raising the critical shear rate. At
5
C,
the STF transitions into a gel-like state. Mechanistic analysis confirms that solvent
viscosity is not the dominant factor; instead, interparticle interactions and
temperature-induced evolution of the solvation layer are identified as the key
mechanisms. This work quantitatively reveals how solvation layer thickness varies
with temperature: a thicker layer at low temperatures promotes the formation of
stable force chains, leading to high friction and shear stress, whereas a thinner layer
at high temperatures allows hydrodynamic clusters to dominate, resulting in a
weaker stress response. The peak viscosity follows the Arrhenius model. These
findings elucidate the temperature-dependent link between macroscopic properties
and microstructure in STFs, providing a theoretical basis for designing STFs for use
in varying thermal environments.
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China-Pakistan Belt and Road Joint
Laboratory on Smart Disaster Prevention of Major
Infrastructures
School of Civil Engineering
Southeast University
Nanjing, 210096
China
Shenzhen Research Institute
Southeast University
Shenzhen, 518063
China
China-Pakistan Belt and Road Joint
Laboratory on Smart Disaster Prevention of Major
Infrastructures
School of Civil Engineering
Southeast University
Nanjing, 210096
China
Jiangsu Key Laboratory of Mechanical
Analysis for Infrastructure and Advanced Equipment
School of Civil Engineering
Southeast University
Nanjing, 210096
China
China-Pakistan Belt and Road Joint
Laboratory on Smart Disaster Prevention of Major
Infrastructures
School of Civil Engineering
Southeast University
Nanjing, 210096
China
Shenzhen Research Institute
Southeast University
Shenzhen, 518063
China
China-Pakistan Belt and Road Joint
Laboratory on Smart Disaster Prevention of Major
Infrastructures
School of Civil Engineering
Southeast University
Nanjing, 210096
China
Shenzhen Research Institute
Southeast University
Shenzhen, 518063
China
China-Pakistan Belt and Road Joint
Laboratory on Smart Disaster Prevention of Major
Infrastructures
School of Civil Engineering
Southeast University
Nanjing, 210096
China
China-Pakistan Belt and Road Joint
Laboratory on Smart Disaster Prevention of Major
Infrastructures
School of Civil Engineering
Southeast University
Nanjing, 210096
China